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The Hotchkiss Revolving Gun

- G. F. B., in Ber. Berl. Chem. Ces.

Schoene has given the results of an extended series of experiments on the use of thallium paper for estimating approximately the oxidizing material in the atmosphere, whether it be hydrogen peroxide alone, or mixed with ozone, or perhaps also with other constituents hitherto unknown. The objection to Schönbein's ozonometer (potassium iodide on starch paper) and to Houzeau's ozonometer (potassium iodide on red litmus paper) lies in the fact that their materials are hygroscopic, and their indications vary widely with the moisture of the air. Since dry ozone does not act on these papers, they must be moistened; and then the amount of moisture varies the result quite as much as the amount of ozone. Indeed, attention has been called to the larger amount of ozone near salt works and waterfalls, and the erroneous opinion advanced that ozone is formed when water is finely divided. And Böttger has stated that ozone is formed when ether is atomized; the fact being that the reaction he observed was due to the H2O2 always present in ether. Direct experiments with the Schönbein ozonometer and the psychrometer gave parallel curves; whence the author regards the former as only a crude hygrometer.

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