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Detection of Alcohol in Transparent Soaps

- H. Jay

It appears that every article manufactured with the aid of alcohol is required on its introduction into France to pay duty on the supposed quantity of this reagent which has been used in its preparation. Certain transparent soaps of German origin are now met with, made, as is alleged, without alcohol, and the author proposes the following process for verifying this statement by ascertaining--the presence or absence of alcohol in the manufactured article: 50 grms. of soap are cut into very small pieces and placed in a phial of 200 c.c. capacity; 30 grms. sulphuric acid are then added, and the phial is stoppered and agitated till the soap is entirely dissolved. The phial is then filled up with water, and the fatty acids are allowed to collect and solidify. The subnatant liquid is drawn off, neutralized, and distilled. The first 25 c.c. are collected, filtered, and mixed, according to the process of MM. Riche and Bardy for the detection of alcohol in commercial methylenes, with ½ c.c. sulphuric acid at 18° B., then with the same volume of permanganate (15 grms. per liter), and allowed to stand for one minute.

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