Wi-Fi stations communicate by sending each other data packets: blocks of data individually sent and delivered over radio. As with all radio, this is done by the modulating and demodulation of carrier waves. Different versions of Wi-Fi use different techniques, 802.11b uses DSSS on a single carrier, whereas 802.11a, Wi-Fi 4, 5 and 6 use multiple carriers on slightly different frequencies within the channel (OFDM).
As with other IEEE 802 LANs, stations come programmed with a globally unique 48-bit MAC address (often printed on the equipment) so that each Wi-Fi station has a unique address.
The MAC addresses are used to specify both the destination and the source of each data packet. Wi-Fi establishes link-level connections, which can be defined using both the destination and source addresses. On the reception of a transmission, the receiver uses the destination address to determine whether the transmission is relevant to the station or should be ignored. A network interface normally does not accept packets addressed to other Wi-Fi stations.

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